{"product_id":"radical-brook-rearrangement-9783527354634","title":"Radical Brook Rearrangement","description":"\u003cp\u003e\u003cb\u003eIn-depth monograph presenting innovative radical methodologies in the Brook rearrangement and their utility in organic synthesis\u003c\/b\u003e\u003c\/p\u003e \u003cp\u003e\u003ci\u003eRadical Brook Rearrangement\u003c\/i\u003e chronicles the evolution of radical Brook rearrangements, synthesizes recent advances in the field, and outlines future research directions. The book focuses on three key reactive intermediates — α-siloxy radicals, siloxycarbenes, and silenes — providing detailed analyses of their generation methods, substrate scope, mechanistic insights, and synthetic applications, along with practical experimental protocols.\u003c\/p\u003e \u003cp\u003eReaders will find insights on alkoxy radical generation, photocatalytic systems, and the selection of radical\/carbene acceptors. This book deliberately focuses on radical processes, excluding anionic pathways.\u003c\/p\u003e \u003cp\u003eWritten by a team of highly qualified researchers in the field, \u003ci\u003eRadical Brook Rearrangement \u003c\/i\u003eincludes information on:\u003c\/p\u003e \u003cul\u003e \u003cli\u003eGeneration of siloxycarbenes for metal siloxycarbene reaction, with information on aminooxycarbene reactions\u003c\/li\u003e \u003cli\u003eGeneration of siloxycarbenes for nucleophilic addition reaction, covering aldehydes and ketones as electrophiles and other electrophilic reagents\u003c\/li\u003e \u003cli\u003eGeneration of α-siloxy silyl radicals with (TMS)3SiOH, covering photoredox reactions and metallaphotoredox reactions with (TMS)3SiNHAd\u003c\/li\u003e \u003cli\u003eGeneration of α-siloxy radicals with α-silyl alcohol, covering metal-free, metal-catalyzed, photocatalyzed, and electrophotocatalyzed reactions\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eContaining cutting-edge research discoveries on the subject, \u003ci\u003eRadical Brook Rearrangement\u003c\/i\u003e is an essential reference for chemists across specializations, materials scientists, and professionals in the pharmaceutical industry.\u003c\/p\u003e","brand":"Xiao Shen","offers":[{"title":"Default Title","offer_id":56489597206870,"sku":"9783527354634","price":140.62,"currency_code":"EUR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0886\/3206\/6390\/files\/9783527354634.jpg?v=1793913284","url":"https:\/\/www.englishbook.fi\/products\/radical-brook-rearrangement-9783527354634","provider":"Bookshop","version":"1.0","type":"link"}